The bauxite (alumina content ∼5459 wt%) used as the raw material in the Bayer process for the synthesis of alumina was obtained from a mine at Weipa in Queensland, bauxite ores were crushed to a particle size of <10 μm using an attrition mill. Table 1 lists the composition of bauxite supplied from the support company. A 5 N sodium hydroxide solution was used for the ...
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For the same grade of bauxite ore, using the traditional Bayer process, the theoretical maximum alumina dissolution rate is % and the Na 2 O mass fraction in the slag is about % (A/S = 1 and N/S = in the red mud), while the actual dissolution rate of the Bayer process bauxite ore in this alumina plant is about 70%, which shows ...
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Bayer process is about the production of alumina through the refining of aluminum ore (bauxite). The red mud is insoluble slurry waste that contains different types of oxides. Tremendous amount of this slurry is disposed every year (Marwaha et al., 2018 ).
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The Bayer process is used for producing alumina (Al 2 O 3) from bauxite process was developed and patented by Karl Josef Bayer in 1887 [], which led to a dramatic reduction in the cost of aluminium process involves the following operations: mining, dissolution of the alumina at elevated temperatures, the addition of flocculants, precipitation of pure gibbsite, regeneration of ...
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It is well known that the Bayer process is the main method to extract alumina from the bauxite in the world [19]. However, Bayer process is only suitable for the treatment of high grade bauxite ore. With the development of alumina production capacity, the resources of high quality bauxite are decreasing year by year [10, 11].
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3 ), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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Alumina Extraction Problem. In the standard Bayer Process for refining bauxite to produce alumina, the dissolution of the alumina in the ore to form sodium aluminate is accomplished in autoclaves under high pressures varying from 70 to 200 pounds per square inch. However, some lateritic bauxite ores are readily soluble in caustic, making it ...
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Bauxite is the major ore for aluminum production, and mainly consists of aluminum hydroxides and oxidehydroxides, iron oxides and oxidehydroxides, clay minerals, silicon dioxide and titanium dioxide, often in various polymorphic mineral phases. 7,8 The concentration of gallium in bauxite ranges from below 10 ppm to over 800 ppm, with an ...
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One of the potential sources of rareearth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red ...
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While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is principally related to the bauxite organic carbon concentration and composition, and to the ...
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The Bayer's process of alumina extraction involves digestion of bauxite with caustic soda at temperatures ranging from 100 to 250 °C, depending on the form of alumina in the bauxite, gibbsitic, boehmitic or diasporic. ... Concentration of bauxite fines via gravity concentration. Rem. Revista la de Minas 62(3), 277281 (2009 ...
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Bayer's Process of Concentration of Bauxite: This process is applied when bauxite contains more Fe 2 O 3 am less SiO 2. This finely ground calcined ore is digested with 45% NaOH solution in an autoclave under 80 lbs pressure at 150°C for ~ 8 hours. When Al 2 O 3 and SiO 2 go into solution as NaAlO 2 and Na 2 iO 3 respectively. The hot ...
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JOM The problem that sulfur causes in alumina production using the Bayer process can be eliminated by adding sodium nitrate, ... Padilla et al. reported that highsulfur bauxite generally refers to the usual bauxite with a sulfur concentration of more than %. 3 The main sulfur minerals in bauxite are pyrite (FeS 2) and its isoforms ...
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During the electrolysis process, the potential of the cathode relative to the reference electrode was measured as a function of the current at different concentrations of solid (100300 g L −1) and suspension temperatures (95120 °C).
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Aluminum production from bauxite is achieved with the Bayer process, which is a hydrometallurgical method. However, in the Bayer process, in time, it is possible to encounter problems such as the formation of excessive amounts of red mud in aluminum production, its environmental risks, its requirement of large storage sites, the excessive production of reactants by ores with low silica modulus ...
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The research on pressure leaching started in 1887. Karl Josef Bayer was the first one who proposed to leaching bauxite with sodium hydroxide solution at a temperature of 413453 K to obtain sodium ...
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Bayer's method: In this method, bauxite powder is taken and concentrated (45%) and sodium hydroxide solution is added and then heated in a closed vessel at 433 K temperature and 5 to 6 bars of pressure, for 6 to 8 hours, so that aluminium oxide present in bauxite is converted into sodium aluminate which is soluble in water. In bauxite, in ...
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The alumina extraction and iron minerals' comprehensive utilization of technology that could replace the current Bayer process have not yet been formed. In the current Bayer digestion process, gibbsitic bauxite was digested at a temperature, alkali concentration, and time of 100150 °C, 120190 g/L, and 1090 min, respectively.
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The first step is to heat the bauxite ore to temperatures of 200°c along with a sodium hydroxide solution. This will convert the aluminium oxide to a solution of sodium aluminate. The silica will dissolve itself in the process. The chemical equation is. Al 2 O 3 + 2 NaOH → 2 NaAlO 2 + H 2 O.
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This paper proposes a novel approach to sulfur removal by adding aluminum in the bayer process of highsulfur bauxite. The effects of aluminum dosage on the concentrations of different valence sulfur in sodium aluminate solution were investigated at length to find that highvalence sulfur (S 2 O 3 2−, SO 3 2−, SO 4 2−) concentration in sodium aluminate solution decreases, but the ...
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The Bayer process is the main method of alumina production worldwide. The use of lowquality bauxites for alumina production results in the formation of a significant amount of technogenic waste—bauxite residue (BR). The Bayer reductive method is one possible way to eliminate BR stockpiling, but it requires highpressure leaching at temperatures higher than 220 °C.
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Solution. The correct option is D Leaching. Bauxite ore is concentrated by the process of leaching. It is a process in which a suitable solution is added to the ore. A chemical reaction takes place between ore and solution in which the ore dissolves in the solution. The insoluble impurities are filtered off.
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Red mud is a byproduct of alumina production, and its disposal can have severe environmental consequences. This study experimentally investigates the feasibility of using red mud from the Bayer process for cemented paste backfill (CPB). Different binders and activators were used to improve the mechanical properties, water resistance, and environmental behaviors of red mudbased CPB. In ...
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The aim of this work was to achieve an understanding of the distribution of selected bauxite trace elements (gallium (Ga), vanadium (V), arsenic (As), chromium (Cr), rare earth elements (REEs), scandium (Sc)) in the Bayer process. The assessment was designed as a case study in an alumina plant in operation to provide an overview of the trace elements behaviour in an actual industrial setup.
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Crushed bauxite is treated with moderately concentrated sodium hydroxide solution. The concentration, temperature and pressure used depend on the source of the bauxite and exactly what form of aluminum oxide it contains. Temperatures are typically from 140°C to 240°C; pressures can be up to about 35 atmospheres.
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Bauxite Al 2 O 2 O; Corundum Al 2 O 3; Cryolite Na 3 AlF 6; Metallurgy of Aluminium. Aluminium is mostly extracted from its bauxite ore. Dressing of Ore. The ore is mechanically crushed and pulverized. Concentration of ore. The bauxite ore contains ferric oxide and silica as impurities.
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Bauxite residue is the byproduct of alumina production and is generated in the Bayer process when bauxite is digested in hot NaOH under elevated temperature and pressure. ... H 2 C 2 O 4 concentration, contact time and temperature had the most pronounced effect on the extracted Ga (ranging from to mg/kg while leaving the other factors ...
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The chemical and physical properties of bauxite residues are determined by the nature of the bauxite and the effect of the Bayer process. The technology and operating procedures at individual refineries ... together with a wide range of other oxides which will vary according to the country of origin of the bauxite. The high concentration of ...
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