Aluminum, which has the outstanding advantages of light weight and corrosion resistance, has a wide range of use in industries including aircraft, construction, automobile, and so on [].Unlike the iron direct extraction from iron ore, pure powder alumina should be firstly extracted from bauxite by alkali methods (Bayer process and sintering process), and then aluminum is produced through ...
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Iron and alumina can be separated from bauxite residue and calcite selfhardened reduced pellets through simultaneous magnetic separation and alkali leaching. Bauxite residue and calcite selfhardened pellets were reduced nonisothermally by hydrogen gas to obtain metallic iron. Thereafter, the fine grounded reduced pellet powder was leached with a simultaneous magnetic stirrer, while two ...
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the Bayer process [4]. This process is based on the alkaline leaching of aluminumbearing ores (mostly bauxite) with sodium hydroxide solution. At this high pH value and elevated temperature and pressure, aluminum hydroxides from bauxite dissolve selectively as following Eq. 1 (in this case gibbsite), while most of the other compounds remain
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The leaching process with dilute HNO 3 was performed at pilot scale and optimized for the extraction of scandium from bauxite residue ( OchsenkühnPetropoulou et al., 2002 ). Xue et al. (2010) found that at a reaction temperature of 90 °C and an L/S ratio of 3:1, over 80% of the scandium in bauxite residue could be leached by H 2 SO 4.
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Bauxite reaction residue (BRR) produced from the polyaluminum chloride (PAC) coagulant industry is a solid acidic waste that is harmful to environment. A low temperature synthesis route to convert the waste into water glass was reported. Silica dissolution process was systematically studied, including the thermodynamic analysis and the influence of calcium and aluminum on the leaching of ...
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The ultimate outcomes of the process are the synthesis of alumina powder and its advanced materials by a costeffective and industrially viable method. ... this process doesn't look compatible with laterite where the iron content is much higher than typical lowgrade bauxite. Hence, an alternative acid leaching extraction was planned ...
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In some cases, the impure ore is treated with a suitable reagent, such as an acid or a base. Because of that, the ore particles dissolve due to leaching, but the gangue impurities do not react. This process is a solidliquid extraction process, and the following example illustrates the procedure of this process: Leaching of alumina from bauxite:
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Primary aluminum production is achieved by the combination of two metallurgical processes: (a) the Bayer process, which refines bauxite to metallurgicalgrade alumina (MGAl 2 O 3), and (b) the HallHéroult process, which produces aluminum metal by electrolytically reducing MGAl 2 O 3 in a cryolite bath. Increasing the sustainability of both these processes and of the entire primary ...
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Red mud, also referred to as bauxite residue, is the largest process waste produced during alumina production from bauxite ore by the Bayer method. Approximately 12 tons of red mud are produced ...
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This method is based on the leaching of precrushed bauxite in alkaline solutions. After leaching, aluminum hydroxide separates from the aluminate solution and is then calcinated to produce alumina. Highquality bauxites with an Al 2 O 3 to SiO 2 mass ratio of more than 8 are required as a raw material for alumina production by the Bayer process .
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The extraction of the metal from bauxite involves the three main steps. Concentration of ore is done by leaching which helps in removing impurities like F e2O3,SiO2, etc. Bauxite is treated with N aOH to form sodium aluminate which on further reaction with CO2 gives pure Alumina. Electrolytic reduction of pure alumina takes place in iron box ...
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The application of bauxite enrichment in the Bayer process before leaching for bauxites from Guinea and Sierra Leone is due to the loss of alumina or alkali in the red mud.
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In the leaching of Alumina from bauxite, concentration of the ore is done by digesting the powdered ore with NaOH and then it is later reacted with CO2 gas. Consider the major impurities presents related to SiO2 is leached out along with Al2O3 as silicate and aluminate on reaction with Iron oxides and titanium oxide are insoluble in NaOH and are left behind as
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Introduction. Bauxite is the major ore for aluminum production. Alumina is extracted from bauxite by the Bayer process. The waste slurry generated in this process is called red mud and its solid fraction is called bauxite residue. About 12 metric tonnes of bauxite residue is generated for each tonne of alumina produced (Kumar et al., 2006).
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1. Introduction. Red mud (RM) is a waste generated during bauxite processing for alumina production. The most common method for bauxite processing is the Bayer process, where raw material is digested under high pressure by NaOH to obtain a pregnant sodium aluminate solution [].During highpressure leaching, nonsoluble elements such as iron, titanium, and refractory or precipitated during ...
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Hall's process for leaching of alumina from bauxite: (1) Bauxite ore and sodium carbonate are fused toghether to convert aluminium oxide into soluble sodium metaaluminate. The insoluble residue contains the impurities of silica and iron oxide. The fused mass is treated with water.
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One of the potential sources of rareearth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red ...
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The separation of the alumina from the impurities in the bauxite ore is usually accomplished by the Bayer Process. In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue.
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The Bayer process is used for refining bauxite to smelting grade alumina, the precursor to aluminum. Typically, depending upon the quality of the ore, between and tonnes of bauxite is required to produce 1 ton of alumina. The Bayer process involves the digestion of crushed bauxite in the concentrated sodium hydroxide (caustic) solution at
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A bauxite residue typically contains 1525% of alumina depending on the origin of its ore and process conditions. Along with alumina, it also contains iron, titanium and rare earth elements ...
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The important processes developed for the recovery of alumina from these sources are acid leaching and alkaline leaching processes. The acid leaching is known as the most efficient in which thermal and mechanical activation are included for improving the performance of the process.
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The extraction process ( digestion) converts the aluminium oxide in the ore to soluble sodium aluminate, NaAlO 2, according to the chemical equation : Al 2 O 3 + 2 NaOH → 2 NaAlO 2 + H 2 O This treatment also dissolves silica, forming sodium silicate : 2 NaOH + SiO 2 → Na 2 SiO 3 + H 2 O The other components of Bauxite, however, do not dissolve.
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To prevent this, a desilication process to reduce the amount of silicon in solution is conducted prior to precipitating hydrated alumina. In the Bayer process, bauxite ores are pressure leached at a high temperature (100250 °C) using sodium hydroxide solution. The leachate solution is then cooled and seeded to precipitate alumina hydrates.
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