Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O basis of the Bayer process is an understanding of the characteristics of the sodiumhydroxide—sodiumaluminate solution relationship, namely its ability to keep sodiumaluminate in a dissolved state over a wide ...
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The Bayer process is used for producing alumina (Al 2 O 3) from bauxite process was developed and patented by Karl Josef Bayer in 1887 [], which led to a dramatic reduction in the cost of aluminium process involves the following operations: mining, dissolution of the alumina at elevated temperatures, the addition of flocculants, precipitation of pure gibbsite, regeneration of ...
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The Bayer process produces pure aluminium hydroxide from bauxite. As shown in the figure below, this process utilises the different thermodynamic properties of the caustic soda aluminium hydroxide system and typically consists of the following stages: bauxite crushing grinding, leaching, physical separation, precipitation and ...
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. The aluminium oxide must be further purified before it can be refined ...
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Bauxite via the Bayer process. This process will be briefly introduced in the following, as well as the reduction to aluminium, the anodes production and further steps of primary production. Alumina Production (Bayer Process) The aluminium production starts with the production of alumina from bauxite according to the socalled Bayer process.
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Introduction. Bauxite residue, or red mud, is a solid waste produced from the alumina refining of bauxite ore. Red mud is mostly collected from the Bayer process which uses sodium hydroxide to dissolve the aluminium silicate. Typically, about 1 to tonnes of red mud remains from the production of 1 t of alumina (Zhang et al., 2011).
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The principal components of bauxite ores are aluminum, iron, and siliconbearing minerals. In the Bayer process for recovery of alumina from bauxite,1 aluminum is dissolved into hot alkaline solution whilst iron is relatively insoluble. "Reactive silica" in the form of silicate minerals, such as kaolinite, typically dissolves and reprecipitates as sodium aluminum hydrosilicate, known as ...
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The major portions of the impurity enter the Bayer process through bauxite. Beyond the critical levels the impurities alter the kinetics of the process. Among the various impurities, organic carbon is the most prominent one that affects the precipitation operation and the product quality, depending on the level of organic with respect to the ...
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The Bayer process for alumina production generates more than 160 million tons of bauxite residue annually. The current global stockpiles of bauxite residue have reached more than 4 billion tons with less than 2% annual recycling rate. Critical elements such as Sc and Y present an opportunity to explore bauxite residue as a secondary resource; however, low concentration affects the process ...
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The Bayer Process, developed by Carl Josef Bayer. is the principal industrial means of refining bauxite to produce alumina (aluminium oxide). In this process, aluminium ore is treated with concentrated sodium hydroxide to form a soluble sodium aluminate. Sodium aluminate is filtered, and the filtrate on heating with water gives aluminium hydroxide.
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The Bayer process is not easily explained in brief. This method of obtaining alumina from bauxite ore is complex and involves a lengthy succession of chemical reactions, with the process varying slightly depending on the makeup of the unique source of bauxite ore. Crushed and washed bauxite ore must first go through a process to remove any ...
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The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3 ), the precursor to aluminium. The process was developed and patented by Karl Josef Bayer 110 years ago, and has become the cornerstone of the aluminium production industry worldwide. Production of alumina reached megatonnes (Mt) worldwide by the end of 1997 ...
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The Bayer Process is the most economic means of obtaining alumina from bauxite. Other processes for obtaining alumina from metal ores are also in use in some refineries, particularly in China and Russia, although these make up a relatively small percentage of global production. The process stages are: 1. Milling
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In the Bayer process, bauxite ore is digested in a highly concentrated caustic soda solution, usually at elevated temperatures and pressures. The process relies upon the lower solubility of the hydroxides of most metals relative to aluminium, but under these conditions it is inevitable
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These refineries use the Bayer Process to extract aluminum hydroxide from the bauxite using hot caustic liquor. Aluminum oxide, Al 2 O 3, is a typical amphoteric oxide, which dissolves in a strong acid and a strong base.
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The Bayer process for alumina production generates more than 160 million tons of bauxite residue annually. The current global stockpiles of bauxite residue have reached more than 4 billion tons ...
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The Bayer process, the production of pure aluminium oxide hydrate (or more chemically formulated aluminium hydroxide) from bauxite, and the calcination process, the production of pure aluminium oxide from the aluminium oxide hydrate. However, these two processes are often combined in books and the media and referred to as "the Bayer ...
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Bayer process liquors are supersaturated not only with alumina but also with contaminants such as silica and oxalate which are derived from digestion of the bauxite ore with caustic liquor; such ...
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Alumina Extraction Problem. In the standard Bayer Process for refining bauxite to produce alumina, the dissolution of the alumina in the ore to form sodium aluminate is accomplished in autoclaves under high pressures varying from 70 to 200 pounds per square inch. However, some lateritic bauxite ores are readily soluble in caustic, making it ...
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The Bayer process holds an exclusive status for alumina extraction, but a massive amount of caustic "red mud" waste is generated. In this work, three oxalate reagents: potassium hydrogen oxalate (KHC 2 O 4), potassium tetraoxalate (KHC 2 O 4 ·H 2 C 2 O 4), and oxalic acid (H 2 C 2 O 4) were investigated for the Al and Fe extraction process from NIST SRM 600 AustralianDarling range ...
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The Bayer process is basically used for the extraction of aluminum hydrate from the bauxite ores with the mass ratio of alumina to silica (A/S) above 9. The sinter process is widely used to process the poorgrade diasporic bauxite ores with A/S below 7, in China and Russia, by sintering the bauxite ore with sodium carbonate and limestone to ...
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BAUXITE TO ALUMINA: THE BAYER PROCESS An Introductory Text 1. Introduction Aluminium is the most abundant metal in the Earth's crust. Unlike metals such as copper and gold, it is never found by itself, but always in combination with the most abundant element, oxygen, and often with the second and fourth most abundant elements, silicon and iron.
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The sulfur in highsulfur bauxite not only pollutes the environment but also harms alumina production. This study investigated the removal of sulfur from highsulfur bauxite by adding Zn or ZnO during the Bayer process. The results showed that the different valence sulfur (S2−, S2O32−, SO32−, and SO42−) in sodium aluminate solution can be effectively removed by adding Zn during the ...
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