direct acid leaching are the consumption of large amounts of acid for neutralization, the handling of large volumes of effluents, and the difficulty in using the bauxite residue after leaching. Recovery of iron prior to leaching can improve the economics of the process. However, high alumina in the bauxite residue increases the flux and acid
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Gibbsitic bauxite from Australia was leached by hydrochloric acid in this work. Analysis on kinetics for the extraction of Al 2 O 3 was quantitatively studied. It was concluded that the hydrochloric acid leaching process of gibbsitic bauxite was controlled by chemical reaction. Moreover, the mechanism for the dissolution followed the equation ...
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A bauxite residue typically contains 1525% of alumina depending on the origin of its ore and process conditions. Along with alumina, it also contains iron, titanium and rare earth elements ...
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Abstract The recovery of major components of bauxite residue by carbothermic reduction at °C and subsequent slag leaching in a Na3CO3(aq) solution is studied. Iron recovers primarily to pigiron and lime is added to tune the calcium aluminate slags towards the highly leachable mayenite phase. The concentration of aluminum in the leachate correlates well with the occurrence of ...
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Bauxite residue is the solid residue generated in the Bayer process for aluminum production. ... To uncover the mechanism of REEs leaching process from bauxite residue in the H 2 SO 4 system ...
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Bauxite residue (red mud) is an alkaline waste derived from the industrial process for extraction of alumina from bauxite ore. Some bauxite residues contain considerable concentrations of critical metals, for example, rare earth elements. Lithium in red mud was also reported as a potential resource. In the current study, a Lirich red mud was leached using acetic acid to investigate the ...
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The major commercial technology for the production of smelter grade alumina has conventionally been the Bayer process which converts bauxite ore, an aluminum containing ore which typically contains about 50 % Al 2 O 3, into smelter grade alumina that contains over % Al 2 O potential source of aluminum that is receiving renewed attention is coal fly ash (CFA), which is a by ...
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Revised Date: 14 March 2021. Highiron bauxite with low A/S ratio cannot be extracted economically by Bayer process. Taking a lowgrade gibbsite ore abroad as the research object, the acid leaching performance of gibbsite was studied by using hydrochloric acid as leaching medium. The effects of ore particle size, liquidsolid ratio, time and ...
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As an alkaline leaching method, roastingleaching process is a potential way to separate silica and alumina in primary alumina/silicabearing minerals (Herbert and Hans, 1960, Luo et al., 2016, Qiu et al., 2004, Rayzman et al., 2003, Smith, 2009).After roasting at >980 °C, the silica from the decomposition of kaolinite can be selectively extracted atmospherically by alkaline solution, and ...
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However, high alumina in the bauxite residue increases the flux and acid consumption. Therefore, alumina needs to be removed by alkali roasting prior to smelting in order to decrease the flux and acid consumption. The alkali roastingsmeltingleaching process allows recovery of aluminum, iron, titanium, and REEs from bauxite residue.
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Recovering iron and aluminum efficiently is the key route to utilize lowgrade highiron bauxite. Aiming to optimize the iron separating process and elevate both Fe and Al recovery ratio, three different FeAl recovery processes with different magnetic roasting (R), Bayer leaching process (L) and magnetic separation (S) orders were investigated. The studied processes include bauxite leaching ...
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Primary aluminum production is achieved by the combination of two metallurgical processes: (a) the Bayer process, which refines bauxite to metallurgicalgrade alumina (MGAl 2 O 3), and (b) the HallHéroult process, which produces aluminum metal by electrolytically reducing MGAl 2 O 3 in a cryolite bath. Increasing the sustainability of both these processes and of the entire primary ...
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In general, the lithium content in bauxite ore is negatively correlated with the alumina content,, the lithium content in bauxite decreases with increasing Al 2 O 3 content. 25,28 Lithium in bauxite tailings 27 can be recovered using acid leaching; however, this leaching process is not selective and the leachate purification process is ...
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The separation of the alumina from the impurities in the bauxite ore is usually accomplished by the Bayer Process. In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue. The aluminate solution is then decomposed producing Al (OH)3 ...
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The Bayer red mud (BRM), a highly alkaline solid residue, is produced during the Bayer process for extraction of alumina from bauxite ores (Zhu et al., 2012). Approximately t of BRM is generated per ton of alumina from the process, depending on the original properties of bauxite and operating conditions (Li et al., 2016).
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For complete valorization of bauxite residue, iron content needs to be lowered by recovering it through smelting reduction followed by slag leaching for the recovery of other metals (, Ti and REEs). Smelting reduction process becomes uneconomical with high alumina as it hinders efficient separation of metal and .
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The solution is clarified by filtering off the solid impurities, commonly with a rotary sand trap and with the aid of a flocculant such as starch, to remove the fine particles. The undissolved waste after the aluminium compounds are extracted, bauxite tailings, contains iron oxides, silica, calcia, titania and some unreacted alumina.
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As Hudson Resources reports in a press release posted on 'GlobeNewswire', "this is the key first step in the production of a wastefree smelter grade 'Green Alumina' product for the aluminum industry.". The company aims to provide evidence of an economic process for producing such a product from anorthosite. The anorthosite samples ...
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The important processes developed for the recovery of alumina from these sources are acid leaching and alkaline leaching processes. The acid leaching is known as the most efficient in which thermal and mechanical activation are included for improving the performance of the process.
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The HCl leaching studies of bauxite indicated that as the concentration of HCl acid increases, the iron content reduces substantially, but at the same time, loss of alumina takes place. The change in bauxite colour from reddish brown to light colour indicated leaching of ore. It was found that bauxite of 300 µ size, leached with HCl of 25% ...
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Bauxite residue is the voluminous byproduct of alumina production after Bayer process. Its high alkalinity causes disposal problems and harmful environmental impacts. However, the residue contains . Expand. 23 [PDF] 1 Excerpt; ... During acid leaching of bauxite residue (red mud), the increase in dissolution of rareearth elements ...
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In the leaching of alumina from bauxite, the ore expected to leach out in the process by reacting with N aOH is A T iO2 B ZnO C SiO2 D F e2O3 Solution The correct option is C SiO2 Along with Al2O3, SiO2 too dissolves forming N aSiO3.
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also removes both alumina and soda from the process. Figure 5: A03 Schematic Digestion In the digestion process, caustic soda (NaOH) is used to dissolve the alumina (Al 2 O 3) in the bauxite for later precipitation (recrystallisation) and then calcination. There are two types of bauxite, trihydrate (Gibbsite Al 2 O 2 O) and mono ...
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The generation of bauxite residue during the production of alumina from bauxite ore is considered as one of the major concerns of alumina refineries throughout the world. In Bayer process after digestion of the bauxite ore in hot caustic solution, the bauxite residue is separated, washed, and disposed dry or in a pond.
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Leaching of alumina from bauxite: The process has been successfully applied in the case of bauxite ( (Al_2O__2O)), an ore of aluminium associated with the impurities of iron oxide ((Fe_2O_3)), titanium oxide ((TiO_2)) and sand ((SiO_2)). The powdered ore is leached with concentrated NaOH solution at 473 523 K temperature and 35 ...
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A closedloop valorization process, combining carbothermic smelting and acid baking water leaching was developed to recover scandium, aluminum, and iron from bauxite residue, a major side product of aluminum production. This process employs carbothermic smelting to recover 99% of the iron in the starting residue as crude metallic iron, which can be separated from slag that contains ...
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Red mud is a kind of strong alkaline hazardous slag discharged from aluminum metallurgy industry. In this study, the water immersion with high temperature and high pressure was developed for the selective dealkalization from red mud by adding Mgbased additives. The removal efficiency of alkali could reach 92% by using 12% MgCl2 with 9 mL/g at 250 °C for 60 min. The MgCl2 was the most ...
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Based on lime sintering method, a novel process of alumina production from lowgrade bauxite containing sulfur or fly ash is carried out in this paper. The phase of alumina transforms from 12CaO·7Al 2 O 3 (C 12 A 7) to 4CaO·3Al 2 O 3 ·SO 3 (C 4 A 3 S), whose alumina leaching property is better, through decreasing sinter temperature and time ...
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As a hybrid process, bauxite residue undergoes a reductive smelting process with lime addition in an electric arc furnace in order to generate aluminaenriched slag. This slag is subsequently treated with highpressure caustic leaching at moderated (200300 g/l) and high (572762 g/l) sodium hydroxide concentrations.
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